ارزیابی کارایی جاذب مغناطیسی قابل بازیافت نیکل فریت در حذف آلاینده رنگی از محیط آبی
الموضوعات : تکنولوژی آب و فاضلاب
سیده بهاره عظیمی
1
,
زهرا منصف خوشحساب
2
,
زهرا ایازی
3
1 - گروه ارزیابی و مخاطرات محیط زیست، پژوهشکده محیط زیست و توسعه پایدار، سازمان حفاظت محیط¬زیست، تهران، ایران.
2 - گروه شیمی، دانشگاه پیام نور، قزوین، ایران.
3 - گروه شیمی، دانشکده علوم پایه، دانشگاه شهید مدنی آذربایجان، تبریز، ایران.
الکلمات المفتاحية: تصفیه پساب, فرایند جذب سطحی, نانو ذرات مغناطیسی, نیکل فریت,
ملخص المقالة :
در این پژوهش جاذب مغناطیسی نیکل فریت سنتز و مشخصهیابی شده و برای حذف رنگ از محیط آبی به روش جذب سطحی مورد استفاده قرار گرفته است. به این منظور تاثیر پارامترهای مختلف از قبیل غلظت اولیه رنگ، مقدار جاذب، زمان تماس و pH محلول به روش طراحی آزمایش بررسی، مدل و بهینه شده است. همچنین سینتیک فرایند بر اساس معادلات شبه مرتبه اول و شبه مرتبه دوم بررسی شده و تطابق فرایند با الگوهای جذبی لانگمویر و فراندلیچ مورد ارزیابی قرار گرفته است. مشخصهیابی جاذب سنتز شده نشان داد که جاذب مغناطیسی به طور متوسط nm 18 است. مدل سازی و بهینه سازی فرایند به روش آماری پاسخ سطح (RSM) در قالب طراحی مرکب مرکزی (CCD) انجام شد و نتایج نشان داد که در شرایط بهینه شامل غلظت اولیه رنگ mg/L 110، زمان تماس min 90، مقدار جاذب g05/0 و 3 = pH، مقدار جذب تعادلی mg/g 76/3 (معادل 2/93 درصد بازده حذف رنگ) است. بنابراین، با توجه به ساختار رنگ و نوع جاذب مورد استفاده بازده در شرایط اسیدی بهتر است. بررسی سینتیک و همدمای جذب نشان داد که فرایند از سینتیک شبه مرتبه دوم و همدمای لانگمویر تبعیت کرده و بر اساس معادله لانگمویر مقدار حداکثر ظرفیت جذب رنگ mg/g 1/21 است. با توجه به مغناطیسی بودن جاذب مورد استفاده، در پایان فرایند میتوان جاذب را از محیط به راحتی و با کمترین هزینه جدا کرد.
Abd-Zaid, A. A., Ahmed, L. M., & Mohammad, R. K. (2022). Synthesis of inverse spinel nickel ferrite like-broccoli nanoparticle and thermodynamic study of photo-decolorization of alkali blue 4B dye. Journal of Nanostructures, 12(3), 697-710. doi: 10.22052/JNS.2022.03.022
Ademoriyo, C. O., & Enyoh, C. E. (2020). Batch adsorption studies of sunset yellow and tartrazine using coconut and groundnut shells. J. Biomed. Res. Environ. Sci, 1(5), 163-172. doi: 10.37871/jbres1138
Ali, N. S., Khader, E. H., Abdulrahman, M. A., Salih, I. K., & Albayati, T. M. (2024). Removal of anionic azo dye from wastewater using Fe3O4 magnetic nanoparticles adsorbents in a batch system. Desalination and Water Treatment, 317, 100033. doi:10.1016/j.dwt.2024.100033
Azimi, S. B. (2024). Preparation of Biochar and its Use to Remove Nitrophenol from Aqueous Media by Adsorption Method, Environment And Interdisciplinary Development, 9, 69-81. https://www.sid.ir/journal/issue/297005/en
Ashraf, S., Munir, R., Sayed, M., Muneer, A., Yaseen, M., Zahid, M., & Noreen, S. (2025). Synthesis and applications of green waste-mediated nickel, manganese, cobalt, copper, and zinc green ferrites for wastewater remediation. Biomass Conversion and Biorefinery, 15(17), 24001-24034. doi: 10.1007/s13399-024-05664-5
Bagheri, A., Khabbaz, S. H., & Rafati, A. A. (2024). Comparison of the natural and surfactant-modified zeolites in the adsorption efficiency of sunset yellow food dye from aqueous solutions. Scientific Reports, 14(1), 22511. doi:10.1038/s41598-024-72859-1
Bhatt, A. S., Sakaria, P. L., Vasudevan, M., Pawar, R. R., Sudheesh, N., Bajaj, H. C., et al. (2012). Adsorption of an anionic dye from aqueous medium by organoclays: equilibrium modeling, kinetic and thermodynamic exploration. RSC advances, 2(23), 8663-8671. doi: 10.1039/C2RA20347B
Burda, C., Chen, X., Narayanan, R., & El-Sayed, M. A. (2005). Chemistry and properties of nanocrystals of different shapes. Chemical reviews, 105(4), 1025-1102. doi: 10.1021/cr030063a
Chauhan, P. S., Singh, K., Choudhary, A., Brighu, U., Singh, S., & Bhattacharya, S. (2024). Combined advanced oxidation dye-wastewater treatment plant: design and development with data-driven predictive performance modeling. NPJ Clean Water, 7(1), 15. doi:10.1038/s41545-024-00308-7
Deivayanai, V., Karishma, S., Thamarai, P., Saravanan, A., & Yaashikaa, P. (2024). Efficient red azo dye removal from wastewater using magnetic nanoparticle impregnated Prosopis juliflora biomass: ANN modeling approach. Desalination and Water Treatment, 100746. doi: 10.1016/j.dwt.2024.100746
Donyagard, F., Zarei, A. R., & Rezaei-Vahidian, H. (2017). Application of magnetic carbon nanocomposites to remove melanoidin from aqueous media: kinetic and isotherm studies. Research on Chemical Intermediates, 43, 4639-4655. doi: 10.1007/s11164-017-2902-y
Gopale, S., Kakade, G., Kulkarni, G., Vinayak, V., Jadhav, S., & Jadhav, K. (2020). X-ray diffraction, infrared and magnetic studies of NiFe2O4 nanoparticles. Paper presented at the Journal of Physics: Conference Series. doi: 10.1088/1742-6596/1644/1/012010
Hammood, A. Y., Albehadili, M. H., AL-Tememi, M. K., Majed, A. A., & Radhi, W. A. (2025). Use of nano-magnetic materials for removal of Congo red dye from aqueous solutions. Advances in Natural Sciences: Nanoscience and Nanotechnology, 16(2), 025014. doi: 10.1088/2043-6262/adc977
Hassan, A.A., Ali, M.E.M., Abdel-Latif, S.A. et al. Efficient removal of Remazol Red dye from aqueous solution using magnetic nickel ferrite nanoparticles synthesized via aqueous reflux. Sci Rep 15, 17527 (2025). doi: 10.1038/s41598-025-98478-y
Haridevamuthu, B., Murugan, R., Seenivasan, B., Meenatchi, R., Pachaiappan, R., Almutairi, B. O., et al. (2024). Synthetic azo-dye, Tartrazine induces neurodevelopmental toxicity via mitochondria-mediated apoptosis in zebrafish embryos. Journal of Hazardous Materials, 461, 132524. doi: 10.1016/j.jhazmat.2023.132524
Hassan, M. S., & El-Nemr, K. F. (2013). Dye sorption characters of gamma irradiated foamed ethylene propylene diene monomer (EPDM) rubber/clay composites. Journal of Industrial and Engineering Chemistry, 19(4), 1371-1376. doi: 10.1016/j.jiec.2012.12.042
Hummers Jr, W. S., & Offeman, R. E. (1958). Preparation of graphitic oxide. Journal of the american chemical society, 80(6), 1339-1339. doi: 10.1021/ja01539a017
Jeppu, G. P., & Clement, T. P. (2012). A modified Langmuir-Freundlich isotherm model for simulating pH-dependent adsorption effects. Journal of contaminant hydrology, 129, 46-53. doi: 10.1016/j.jconhyd.2011.12.001
Kapanga, P. M., Nyakairu, G. W. A., Nkanga, C. I., Lusamba, S. N., Tshimanga, R. M., & Shehu, Z. (2024). A review of dye effluents polluting African surface water: sources, impacts, physicochemical properties, and treatment methods. Discover Water, 4(1), 85. doi: 10.1007/s43832-024-00129-2
Khandelwal, D., Rana, I., Mishra, V., Ranjan, K. R., & Singh, P. (2024). Unveiling the impact of dyes on aquatic ecosystems through zebrafish–a comprehensive review. Environmental Research, 119684. doi: 10.1016/j.envres.2024.119684
Kolya, H., & Kang, C.-W. (2024). Toxicity of metal oxides, dyes, and dissolved organic matter in water: implications for the environment and human health. Toxics, 12(2), 111. doi:10.3390/toxics12020111
Kreyling, W. G., Semmler-Behnke, M., & Chaudhry, Q. (2010). A complementary definition of nanomaterial. Nano today, 5(3), 165-168. doi: 10.1016/j.nantod.2010.03.004
Kumari, R., Sircar, A., Dey, S., Qaiyum, M., Bist, N., & Yadav, K. (2024). Sequestration of a food dye (sunset yellow) from wastewater using natural adsorbent: a kinetic, isotherm and interference study. International Journal of Phytoremediation, 26(11), 1716-1727. doi: 10.1080/15226514.2024.2349964
Mahmoodi, N. (2013). Basic Dyes Removal from Aqueous Media by Nickel-Zinc Ferrite Magnetic Nanoparticles. Journal of Textile Science and Technology, 3(1), 29-36, 20.1001.1. doi: 21517162.1392.3.1.5.7
Merrikhpour, H., Mobarakpour, S., & Azimi, S. B. (2022). Adsorption of Cd2+, Cu2+, and Ni2+ onto surfactant modified bentonite. Desalination and Water Treatment, 271, 157-165. doi: 10.5004/dwt.2022.28768
Mustamam, M. K., Elaissari, A., Fatehah, M. O., Aziz, H. A., & Wang, M.-H. S. (2024). Nano Pollutant Properties, Occurrence and Behavior in Water and Wastewater Streams. Industrial Waste Engineering, 279-332. doi: 10.1007/978-3-031-46747-9_12
N Lotha, T., Sorhie, V., Bharali, P., & Jamir, L. (2024). Advancement in sustainable wastewater treatment: A multifaceted approach to textile dye removal through physical, biological and chemical techniques. ChemistrySelect, 9(11), e202304093. doi: 10.1002/slct.202304093
Nasiri, A., Golestani, N., Rajabi, S., & Hashemi, M. (2024). Facile and green synthesis of recyclable, environmentally friendly, chemically stable, and cost-effective magnetic nanohybrid adsorbent for tetracycline adsorption. Heliyon, 10 (2). doi: 10.1016/j.heliyon.2024.e24179
Qiu, M., Qian, C., Xu, J., Wu, J., & Wang, G. (2009). Studies on the adsorption of dyes into clinoptilolite. Desalination, 243(1-3), 286-292. doi: 10.1016/j.desal.2008.04.029
Radaei, E., Alavi Moghaddam, M. R., & Arami, M. (2014). Removal of reactive blue 19 from aqueous solution by pomegranate residual-based activated carbon: optimization by response surface methodology. Journal of Environmental Health Science and Engineering, 12, 1-8. doi: 10.1186/2052-336X-12-65
Roosta, M., Ghaedi, M., Daneshfar, A., Darafarin, S., Sahraei, R., & Purkait, M. (2014). Simultaneous ultrasound-assisted removal of sunset yellow and erythrosine by ZnS: Ni nanoparticles loaded on activated carbon: Optimization by central composite design. Ultrasonics sonochemistry, 21(4), 1441-1450. doi: 10.1016/j.ultsonch.2014.01.018
Royer, B., Cardoso, N. F., Lima, E. C., Vaghetti, J. C., Simon, N. M., Calvete, T., et al. (2009). Applications of Brazilian pine-fruit shell in natural and carbonized forms as adsorbents to removal of methylene blue from aqueous solutions—Kinetic and equilibrium study. Journal of Hazardous Materials, 164(2-3), 1213-1222. doi: 10.1016/j.jhazmat.2008.09.028
Sagadevan, S., Chowdhury, Z. Z., & Rafique, R. F. (2018). Preparation and characterization of nickel ferrite nanoparticles via co-precipitation method. Materials Research, 21, e20160533. doi:10.1590/1980-5373-mr-2016-0533
Satyam, S., & Patra, S. (2024). Innovations and challenges in adsorption-based wastewater remediation: a comprehensive review. Heliyon. doi: 10.1016/j.heliyon.2024.e29573
Shen, Z., Kuang, Y., Zhou, S., Zheng, J., & Ouyang, G. (2023). Preparation of magnetic adsorbent and its adsorption removal of pollutants: an overview. TrAC Trends in Analytical Chemistry, 167, 117241. doi: 10.1016/j.trac.2023.117241
Sobhanardakani, S., & Zandipak, R. (2016). Removal of methyl orange dye from aqueous solutions using NiFe2O4 nanoparticles: equilibrium and kinetic studies, 9, 2, 247-Pe258. http://ijhe.tums.ac.ir/article-1-5566-en.html.
Soleymani, A. R., Tavassoli, A. M., & Rezaei-Vahidian, H. (2023). Assessment of back-side activation of titania thin film using a fixed-bed photocatalytic-reactor: kinetic study, operating cost and ANN modeling. Chemical Engineering Research and Design, 190, 759-776. doi: 10.1016/j.cherd.2022.12.047
Su, C.-C., Pukdee-Asa, M., Ratanatamskul, C., & Lu, M.-C. (2011). Effect of operating parameters on decolorization and COD removal of three reactive dyes by Fenton's reagent using fluidized-bed reactor. Desalination, 278(1-3), 211-218. doi: 10.1016/j.desal.2011.05.022
Vahidian, H. R., Soleymani, A. R., & Parsa, J. B. (2015). Development of a four-layered ANN for simulation of an electrochemical water treatment process. Desalination and Water Treatment, 56(2), 388-398. doi: 10.1080/19443994.2014.937761
Zarei, A., Hedayatinasab, F., & Rezaei‐Vahidian, H. (2020). Photocatalytic degradation of nitro‐aromatic explosives using visible‐light‐activated WO3: Optimization and catalyst modification. Environmental Progress & Sustainable Energy, 39(4), e13386. doi: 10.1002/ep.13386